鐘羽武

男， 中國(guó)科學(xué)院化學(xué)研究所， 教授/研究員/教授級(jí)高工或同等級(jí)別

學(xué)習(xí)/工作經(jīng)歷

1995.09– 1999.07, 南開(kāi)大學(xué)化學(xué)系，本科學(xué)生
1999.09– 2004.07, 中國(guó)科學(xué)院上海有機(jī)所, 博士研究生
2004.09– 2006.09, 日本東京大學(xué)化學(xué)系, 博士后
2006.09– 2009.09, 美國(guó)康奈爾大學(xué)化學(xué)與生物學(xué)系, 博士后
2009.09至今, 中國(guó)科學(xué)院化學(xué)研究所, 研究員

研究領(lǐng)域和興趣

光功能材料與光電化學(xué)，光功能配合物的合成與組裝，近紅外電致變色，混合價(jià)電子轉(zhuǎn)移，有機(jī)功能分子設(shè)計(jì)與合成，電化學(xué)聚合薄膜的制備與應(yīng)用，有機(jī)空穴傳輸材料的合成及其在鈣鈦礦太陽(yáng)能電池中的應(yīng)用。

主要業(yè)績(jī)

光功能配合物是重要的分子材料，在分子光電子學(xué)和光電/電光轉(zhuǎn)換器件中有重要用途。近年來(lái)，圍繞金屬有機(jī)光功能配合物的分子設(shè)計(jì)合成、功能薄膜制備、微納晶體制備及光電性能開(kāi)展工作，取得了如下創(chuàng)新性進(jìn)展：
1. 基于“有機(jī)-無(wú)機(jī)共軛”策略，合成了一系列三芳胺和金屬釕共軛的給-受體電子轉(zhuǎn)移化合物，利用三芳胺和金屬有機(jī)釕之間的強(qiáng)電子耦合，實(shí)現(xiàn)迄今為止多聯(lián)苯橋基誘導(dǎo)的最長(zhǎng)電子轉(zhuǎn)移過(guò)程。發(fā)展了“金屬/有機(jī)共軛”近紅外分子設(shè)計(jì)策略，已被國(guó)內(nèi)外8個(gè)課題組多次使用和借鑒，并擴(kuò)展到三芳胺與釕、鋨、鐵、鈷、鉬、銥等6種不同金屬共軛的分子體系。
2. 利用電化學(xué)聚合以及自組裝成膜，實(shí)現(xiàn)了金屬有機(jī)釕配合物形貌、厚度可控的功能薄膜制備?；谂浜衔锱c電極之間高效的界面電子轉(zhuǎn)移過(guò)程，實(shí)現(xiàn)高性能近紅外電致變色和電信息存儲(chǔ)，在光纖通訊和信息處理方面有重要應(yīng)用前景。發(fā)展的橋聯(lián)配體和電聚合方法被不同課題組用于金屬配合物薄膜的制備。
3. 通過(guò)結(jié)晶驅(qū)動(dòng)組裝法，首次制備了雙組份光功能配合物的高質(zhì)量微納晶體，實(shí)現(xiàn)高效三線態(tài)能量轉(zhuǎn)移和天線放大效應(yīng)，并具備微納尺度光信號(hào)處理功能。通過(guò)改變分子結(jié)構(gòu)與組裝條件，實(shí)現(xiàn)微納晶體形貌與發(fā)光性能的調(diào)控，為納米光子學(xué)奠定重要分子及材料基礎(chǔ)。
近五年（2014 – 2019）發(fā)表通訊作者論文60余篇，包括J. Am. Chem. Soc. 6篇、Angew. Chem. Int. Ed. 4篇、Nat. Commun. 2篇、Chem. Sci. 2篇，應(yīng)邀在Coord. Chem. Rev.、Chem. Rec.等期刊撰寫(xiě)綜述，撰寫(xiě)專(zhuān)著章節(jié)2次。近5年在國(guó)際配位化學(xué)會(huì)議、ACS年會(huì)等重要學(xué)術(shù)會(huì)議上做邀請(qǐng)報(bào)告10余次。迄今共發(fā)表論文140余篇，近五年他引1800次。先后擔(dān)任《中國(guó)科學(xué)：化學(xué)》，Sci. Rep.等4種期刊編委，入選2018年度《中國(guó)科學(xué)》《科學(xué)通報(bào)》優(yōu)秀編委。獲2015年中國(guó)電化學(xué)青年獎(jiǎng)、2019年國(guó)家杰出青年科學(xué)基金、中國(guó)光化學(xué)-泊菲萊優(yōu)秀青年科學(xué)家獎(jiǎng)、盧嘉錫優(yōu)秀導(dǎo)師獎(jiǎng)。

代表成果

論文：
(1) Zhong-Qiu Li, Yu-Duan Wang, Jiang-Yang Shao, Zeyang Zhou, Zhong-Liang Gong, Chuang Zhang, Jiannian Yao and Yu-Wu Zhong*, Electrically Amplified Circularly Polarized Luminescence by a Chiral Anion Strategy. Angew. Chem. Int. Ed. 2023, 62, e202302160.
(2) Zhong-Qiu Li, Zhong-Liang Gong, Tongling Liang, Stefan Bernhard, Yu-Wu Zhong* and Jiannian Yao*, Circularly polarized phosphorescence and photon transport of micro/nanocrystals of ruthenium and iridium complexes with chiral anions. Sci. China Chem. 2023, 66, 2892-2902.
(3) Jiang-Yang Shao?, Dongmei Li?, Jiangjian Shi?, Chuang Ma?, Yousheng Wang?, Xiaomin Liu?, Xianyuan Jiang?, Mengmeng Hao?, Luozheng Zhang?, Chang Liu?, Yiting Jiang?, Zhenhan Wang?, Yu-Wu Zhong*, Shengzhong (Frank) Liu*, Yaohua Mai*, Yongsheng Liu*, Yixin Zhao*, Zhijun Ning*, Lianzhou Wang*, Baomin Xu*, Lei Meng*, Zuqiang Bian*, Ziyi Ge*, Xiaowei Zhan*, Jingbi You*, Yongfang Li and Qingbo Meng*, Recent progress in perovskite solar cells: material science. Sci. China Chem. 2023, 66, 10-64.
(4) Zhong-Qiu Li, Dian-Xue Ma, Fa-Feng Xu, Ti-Xiong Dan, Zhong-Liang Gong, Jiang-Yang Shao, Yong Sheng Zhao, Jiannian Yao and Yu-Wu Zhong*, Selective, Anisotropic, or Consistent Polarized-Photon Out-Coupling of 2D Organic Microcrystals. Angew. Chem. Int. Ed. 2022, 61, e202205033.
(5) Fa-Feng Xu#, Wei Zeng#, Meng-Jia Sun, Zhong-Liang Gong, Zhong-Qiu Li, Yong Sheng Zhao, Jiannian Yao and Yu-Wu Zhong*, Organoplatinum(II) Cruciform: A Versatile Building Block to Fabricate 2D Microcrystals with Full-Color and White Phosphorescence and Anisotropic Photon Transport. Angew. Chem. Int. Ed. 2022, 61, e202116603.
(6) Rui Li, Zhong-Liang Gong*, Qijian Zhu, Meng-Jia Sun, Yanke Che, Jiannian Yao and Yu-Wu Zhong*, A pre-organized monomer-reservoir strategy to prepare multidimensional phosphorescent organoplatinum nanocrystals and suprastructures. Sci. China Chem. 2022, 65, 328-338.
(7) Ming-Hua Li#, Jiang-Yang Shao#, Yan Jiang*, Fa-Zheng Qiu, Shuo Wang, Jianqi Zhang, Guangchao Han, Jilin Tang, Fuyi Wang, Zhixiang Wei, Yuanping Yi, Yu-Wu Zhong*, and Jin-Song Hu*, Electrical Loss Management by Molecularly Manipulating Dopant-free Poly(3-hexylthiophene) towards 16.93% CsPbI2Br Solar Cells. Angew. Chem. Int. Ed. 2021, 60, 16388-16393.
(8) Zhong-Qiu Li, Zhong-Liang Gong, Jiang-Yang Shao, Jiannian Yao and Yu-Wu Zhong*, Full-Color and White Circularly Polarized Luminescence of Hydrogen-Bonded Ionic Organic Microcrystals. Angew. Chem. Int. Ed. 2021, 60, 14595-14600.
(9) Zhong-Liang Gong?, Xuefeng Zhu?, Zhonghao Zhou?, Si-Wei Zhang?, Dong Yang?, Biao Zhao?, Yi-Pin Zhang?, Jianping Deng*, Yixiang Cheng*, You-Xuan Zheng*, Shuang-Quan Zang*, Hua Kuang*, Pengfei Duan*, Mingjian Yuan*, Chuan-Feng Chen*, Yong Sheng Zhao*, Yu-Wu Zhong*, Ben Zhong Tang* and Minghua Liu*, Frontiers in circularly polarized luminescence: molecular design, self-assembly, nanomaterials, and applications. Sci. China Chem. 2021, 64, 2060-2104.
(10) Zhong-Liang Gong, Yu-Wu Zhong*, Handedness-Inverted Polymorphic Helical Assembly and Circularly Polarized Luminescence of Chiral Platinum Complexes. Sci. China Chem. 2021, 64, 788-799.
(11) Tian‐Ge Sun, Zhong‐Liang Gong, Jiang‐Yang Shao*, Yu‐Wu Zhong*, A Star‐Shaped Solvatofluorochromic Pyrene‐Triarylamine Derivative as a Fluorescent Thermometer over a Wide Temperature Range. Chin.J.Chem. 2020, 38, 1515-1520.
(12) Qing Hao, Zhi-Juan Li, Cheng Lu, Bing Sun, Yu-Wu Zhong*, Li-Jun Wan and Dong Wang*, Oriented Two-Dimensional Covalent Organic Framework Films for Near-Infrared Electrochromic Application, J. Am. Chem. Soc. 2019, 141, 19831–19838.
(13) Jian-Hong Tang?, Yueqi Li?, Qingqing Wu?, Zixiao Wang?, Songjun Hou, Kun Tang, Yue Sun, Hui Wang, Heng Wang, Cheng Lu, Xiang Wang, Xiaopeng Li, Dong Wang, Jiannian Yao, Colin J. Lambert*, Nongjian Tao*, Yu-Wu Zhong* and Peter J. Stang*, Single-molecule level control of host-guest interactions in metallocycle-C60 complexes, Nat. Commun. 2019, 10, 4599.
(14) Meng-Jia Sun?, Yingying Liu?, zeng wei, Yong Sheng Zhao*, Yu-Wu Zhong* and Jiannian Yao*, Photoluminescent Anisotropy Amplification in Polymorphic Organic Nanocrystals by Light-Harvesting Energy Transfer. J. Am. Chem. Soc. 2019, 141, 6157-6161.
(15) Zhi-Juan Li, Chang-Jiang Yao and Yu-Wu Zhong*, Near-infrared electrochromism of multilayer films of a cyclomet-alated diruthenium complex prepared by layer-by-layer deposi-tion on metal oxide substrates, Sci. China Chem. 2019, 62, 1675–1685.
(16) Jian-Hong Tang, Zhenfeng Cai, Dong Yan, Kun Tang, Jiang-Yang Shao, Chuanlang Zhan, Dong Wang, Yu-Wu Zhong,* Li-Jun Wan, and Jiannian Yao, A Molecular Quadripod as a Noncovalent Interfacial Coupling Reagent for Forming Immobilized Coordination Assemblies. J. Am. Chem. Soc. 2018, 140, 12337-12340.
(17) Qian-Qing Ge?, Jiang-Yang Shao?,*, Jie Ding, Li-Ye Deng, Wen-Ke Zhou, Yao-Xuan Chen, Jing-Yuan Ma, Li-Jun Wan, Jiannian Yao, Jin-Song Hu*, and Yu-Wu Zhong*, A Two‐Dimensional Hole‐Transporting Material for High‐Performance Perovskite Solar Cells with 20% Average Efficiency. Angew. Chem. Int. Ed. 2018, 57, 10959-10965.
(18) Jian-Hong Tang?, Yue Sun?, Zhong-Liang Gong, Zhong-Yu Li, Zhixuan Zhou, Heng Wang, Xiaopeng Li, Manik Lal Saha*, Yu-Wu Zhong* and Peter J. Stang*, Temperature-Responsive Fluorescent Organoplatinum(II) Metallacycles. J. Am. Chem. Soc. 2018, 140, 7723-7729.
(19) Meng-Jia Sun, Yu-Wu Zhong* and Jiannian Yao*, Thermal-Responsive Phosphorescent Nanoamplifiers Assembled from Two Metallophosphors. Angew. Chem. Int. Ed. 2018, 57, 7820-7825.
(20) Meng-Jia Sun, Yingying Liu, Yaming Yan, Rui Li, Qiang Shi*, Yong Sheng Zhao*, Yu-Wu Zhong* and Jiannian Yao*, In Situ Visualization of Assembly and Photonic Signal Processing in a Triplet Light-Harvesting Nanosystem. J. Am. Chem. Soc. 2018, 140, 4269?4278.
(21) Ce Zhou?, Xingxing Li?, Zhongliang Gong?, Chuancheng Jia, Yuanwei Lin, Chunhui Gu, Gen He, Yuwu Zhong*, Jinlong Yang* and Xuefeng Guo*, Direct observation of single-molecule hydrogen-bond dynamics with single-bond resolution. Nat. Commun. 2018, 9, 807.
(22) Rui Li, Zhong-Liang Gong, Jian-Hong Tang, Meng-Jia Sun, Jiang-Yang Shao, Yu-Wu Zhong* and Jiannian Yao, Triarylamines with branched multi-pyridine groups: modulation of emission properties by structural variation, solvents, and tris(pentafluorophenyl)borane. Sci. China Chem. 2018, 61, 545-556.
(23) Zhong-Liang Gong, Chang-Jiang Yao, Jiang-Yang Shao, Hai-Jing Nie, Jian-Hong Tang, Yu-Wu Zhong*, Redox-responsive carbometalated ruthenium and osmium complexes, Sci. China Chem. 2017, 60, 583-590.
(24) Lin Wang+, Zhong-Liang Gong+, Shu-Ying Li, Wenjing Hong*, Yu-Wu Zhong*, Dong Wang*, Li-Jun Wan, Molecular Conductance through a Quadruple-Hydrogen-Bond-Bridged Supramolecular Junction, Angew. Chem. Int. Ed. 2016, 55, 12393-12397.
(25) Bin-Bin Cui, Jian-Hong Tang, Jiannian Yao, and Yu-Wu Zhong*, A Molecular Platform for Multistate Near-Infrared Electrochromism and Flip-Flop, Flip-Flap-Flop, and Ternary Memory, Angew. Chem. Int. Ed. 2015, 54, 9192-9197.
(26) Zhong-Liang Gong, Yu-Wu Zhong,* Urea-bridged diferrocene: structural, electrochemical, and spectroelectrochemical studies, Sci. China Chem. 2015, 58, 1444-1450.
(27) Bin-Bin Cui, Yu-Wu Zhong*, Jiannian Yao, Three-State Near-Infrared Electrochromism at the Molecular Scale, J. Am. Chem. Soc. 2015, 137 , 4058-4061.
(28) Bin-Bin Cui, Chang-Jiang Yao, Jiannian Yao, Yu-Wu Zhong,* Electropolymerized films as a molecular platform for volatile memory devices with two near-infrared outputs and long retention time, Chem. Sci. 2014, 5, 932-941.
(29) Chang-Jiang Yao，Yu-Wu Zhong*，Hai-Jing Nie，Hector D. Abruna，Jiannian Yao*，Near-IR Electrochromism in Electropolymerized Films of a Biscyclometalated Ruthenium Complex Bridged by 1.2.4.5-Tetra(2-pyridyl)benzene Ligand，J. Am. Chem. Soc. 2011, 133, 20720-20723.
(30) Chang-Jiang Yao，Yu-Wu Zhong*，Jiannian Yao*，Charge Delocalization in a Cyclometalated Bisruthenium Complex Bridged by a Noninnocent 1.2.4.5-Tetra(2-pyridyl)benzene Ligand, J. Am. Chem. Soc. 2011, 133, 15697-15706.

專(zhuān)利：
(1) 鐘羽武; 王宇端; 邵將洋, 一種芴改性鋅卟啉空穴傳輸材料及其制備方法與應(yīng)用, 批準(zhǔn)年份2022，專(zhuān)利號(hào)ZL202110466415.8
(2) 鐘羽武; 龔忠亮, 一種咔唑橋聯(lián)雙核金屬鉑配合物及其制備方法和應(yīng)用, 批準(zhǔn)年份2022，專(zhuān)利號(hào)ZL202110349575 .4
(3) 鐘羽武; 李仲秋，一種白色圓偏振發(fā)光有機(jī)微納晶體材料及其制備方法，批準(zhǔn)年份2022，專(zhuān)利號(hào)ZL202110303685.7
(4) 鐘羽武; 李仲秋; 唐健洪; 龔忠亮，一種深藍(lán)色發(fā)光有機(jī)微納晶體材料及其制備方法，批準(zhǔn)年份2022，專(zhuān)利號(hào)ZL202110127950.0
(5) 鐘羽武; 龔忠亮, 一種離子型手性單核金屬鉑配合物、制備方法及其應(yīng)用, 批準(zhǔn)年份2022，專(zhuān)利號(hào)ZL202010239489.3

著作：
Yu-Wu Zhong, Chun Y. Liu and Jeffrey R. Reimers, Mixed‐Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications, Wiley-VCH GmbH, 2023, Weinheim, Germany.

*以上信息由高級(jí)會(huì)員個(gè)人更新和維護(hù)。