徐柏慶

男， 清華大學(xué)化學(xué)系， 教授/研究員/教授級(jí)高工或同等級(jí)別

學(xué)習(xí)/工作經(jīng)歷

1978,09 - 1982,07： 江西大學(xué)（現(xiàn)南昌大學(xué)） 化學(xué)系，物理化學(xué)專(zhuān)業(yè)本科生
1982,08 - 1985,02： 中國(guó)科學(xué)院大連化學(xué)物理研究所，多相催化專(zhuān)業(yè)碩士研究生
1985,03 - 1988,10： 中國(guó)科學(xué)院大連化學(xué)物理研究所，物理化學(xué)專(zhuān)業(yè)博士研究生
1986,01 - 1988, 04: 日本國(guó)北海道大學(xué)理學(xué)院，日本政府獎(jiǎng)學(xué)金物理化學(xué)專(zhuān)業(yè)博士研究生
1988,10 - 1991,11： 中科院大連化物所，助理研究員（一級(jí)）、催化領(lǐng)域?qū)W術(shù)活動(dòng)領(lǐng)導(dǎo)小組成員兼秘書(shū)。
1991,12 - 1992,09： 大連理工大學(xué)副教授
1992,10 - 1998,04： 大連理工大學(xué)教授, 校務(wù)委員會(huì)委員
1995,03 - 1996,06: 美國(guó)西北大學(xué)催化與表面科學(xué)研究中心, 中國(guó)教育部?jī)?yōu)秀中青年高級(jí)訪(fǎng)問(wèn)學(xué)者
1996,07 - 1997,06: 美國(guó)佐治亞理工大學(xué)化工學(xué)院, research faculty
1997,07 - 1998,04: 美國(guó)西北大學(xué)催化與表面科學(xué)研究中心, research associate
1998,05 - ： 清華大學(xué)化學(xué)系教授、清華大學(xué)一碳化學(xué)與化工國(guó)家重點(diǎn)實(shí)驗(yàn)室主任 (1999－2002), 物理化學(xué)研究所所長(zhǎng) (2002～2017), 教育部長(zhǎng)江學(xué)者獎(jiǎng)勵(lì)計(jì)劃特聘教授 (2016-2019)
2001,12 - 2002,03: 美國(guó)加州大學(xué)伯克利分校, 催化中心訪(fǎng)問(wèn)教授
2002,12 - 2003,05: 香港浸會(huì)大學(xué)化學(xué)系, 香港裘槎基金會(huì)訪(fǎng)問(wèn)學(xué)者

研究領(lǐng)域和興趣

催化物理化學(xué)

主要業(yè)績(jī)

發(fā)現(xiàn)并提出了固體酸堿催化劑表面烷基胺分解轉(zhuǎn)化反應(yīng)的活性與選擇性規(guī)律；闡明了硫酸氧化鋯催化劑上丁烷異構(gòu)化反應(yīng)的質(zhì)子酸催化本質(zhì)；提出和發(fā)展了“納米復(fù)合物型金屬/氧化物”催化劑學(xué)說(shuō)；近年提出了發(fā)展貴金屬節(jié)約型催化劑的新思路，在一些生物質(zhì)平臺(tái)分子的催化增值轉(zhuǎn)化研究中做出了若干新發(fā)現(xiàn)。

代表成果

1. G.-R. Zhang, D. Zhao, Y.-Y. Feng, B.-S. Zhang, D.-S. Su, G. Liu, and B.-Q. Xu*, Catalytic Pt-on-Au nanostructures: Why Pt becomes More Active on Smaller Au Particles, ACS Nano 6, 2226-2236 (2012).
2. Zhao, D; Xu, BQ*, Enhancement of Pt utilization in electrocatalyst using gold nanoparticles, Angew. Chem. Int. Ed. 45: 4955-4959 (2006).
3. Zhang, X; Shi, H; Xu, BQ*, Catalysis by gold: Isolated surface Au3+ ions are active sites for selective hydrogenation of 1,3-butadiene over Au/ZrO2 catalysts, Angew. Chem. Int. Ed. 44, 7132-7135 (2005).
4. Zhang, X; Wang, H; Xu, BQ*; Remarkable nanosize effect of zirconia in Au/ZrO2 catalyst for CO oxidation, J. Phys. Chem. C 109, 9678-9683 (2005).
5. Chai, SH; Wang, HP; Liang, Y; Xu, BQ*, Sustainable Production of Acrolein: Investigation of Solid Acid-Base Catalysts for Gas-phase Dehydration of Glycerol, Green Chemistry 9: 1130- 1136 (2007).
6. Y. Gu, L. Wang, B.-Q. Xu*, H. Shi*. Recent advances in the molecular-level understanding of catalytic hydrogenation and oxidation reactions at metal-aqueous interfaces. Chin. J. Catal. 54: 1-55 (2023).
7. B. Yan, Z. -H. Liu, Y. Liang, B.-Q. Xu*. Acrylic Acid Production by Gas-Phase Dehydration of Lactic Acid over K+-Exchanged ZSM-5: Reaction Variable Effects, Kinetics, and New Evidence for Cooperative Acid–Base Bifunctional Catalysis. Ind. Eng. Chem. Res., 59(39): 17417-17428 (2020).
8. J.-W. Yang, W.-T. Zheng, Z. Hu, M. Zhang, B.-Q. Xu*, Do Olefin Hydrogenation Reactions Remain Structure Insensitive over Pt in Nanostructured Pt-on-Au Catalyst? ACS Catal. 8, 10254-10260 (2018).
9. Zi-Fei Yuan, Wei-Na Zhao, Zhi-Pan Liu and Bo-Qing Xu, NaOH alone can be a homogeneous catalyst for selective aerobic oxidation of alcohols in water, J. Catal. 353, 37-43 (2017).
10. Bo Yan, Li-Zhi Tao, Azhar Mahmood, Yu Liang, Bo-Qing Xu*, Potassium-Ion-Exchanged zeolites for sustainable production of acrylic acid by gas-phase dehydration of lactic acid, ACS Catal. 7, 538–550 (2017).
11. Liu-Liu Shen, Gui-Rong Zhang, Shu Miao, Jingyue (Jimmy) Liu, Bo-Qing Xu*, Core?shell nanostructured Au@NimPt2 electrocatalysts with enhanced activity and durability for oxygen reduction reaction, ACS Catal. 2016, 6, 1680-1690 (2016).
12. B. Yan, L.-Z. Tao, Y. Liang, and B.-Q. Xu*, Sustainable Production of Acrylic Acid: Catalytic Performance of hydroxyapatites for gas-phase dehydration of lactic acid, ACS Catal. 4, 1931-1943 (2014).
13. S.-S. Liu, K.-Q. Sun, and B.-Q. Xu*, Specific selectivity of Au-catalyzed oxidation of glycerol and other C3?polyols in water without the presence of a base, ACS Catal. 4, 2226-2230 (2014).
14. R.-Y. Zhong, K.-Q. Sun, Y.-C. Hong, and B.-Q. Xu*, Impacts of Organic Stabilizers on Catalysis of Au Nanoparticles from Colloidal Preparation, ACS Catal. 4, 3982-3993 (2014).
15. L.-Z. Tao, B. Yan, Y. Liang and B.-Q. Xu*, Sustainable production of acrolein: catalytic performance of hydrated tantalum oxides for gas-phase dehydration of glycerol, Green Chem. 15, 696-705 (2013).
16. K.-Q. Sun, Y.-C. Hong, G.-R. Zhang, B.-Q. Xu*, Synergy between Pt and Au in Pt-on-Au (Ptm^Au) Nanostructures for Chemoselective Hydrogenation Catalysis, ACS Catal. 1, 1336-1346 (2011).
17. X. Zhang, H. Shi, B.-Q. Xu*, Vital roles of hydroxyl groups and gold oxidation states in Au/ZrO2 catalysts for 1,3-butadiene hydrogenation, J. Catal. 279, 75-87 (2011).
18. Nan-Hong Xie, Xiang-Hui Yan, Bo-Qing Xu*, Is Ammonium peroxydisulfate indispensable for preparation of aniline-derived iron-nitrogen-carbon electrocatalysts? ChemSusChem 9, 2301-2306 (2016).
19. X.-H. Yan, and B.-Q. Xu*, Mesoporous carbon material co-doped with nitrogen and iron (Fe–N–C): high-performance cathode catalyst for oxygen reduction reaction in alkaline electrolyte, J. Mater. Chem. A 2, 8617-8622 (2014).
20. H. Zhang, B. Yao, L. Zhao, D.-X. Wang, B.-Q. Xu, M.-X. Wang*, Direct Synthesis of High-Valent Aryl-Cu(II) and Aryl-Cu(III) Compounds: Mechanistic Insight into Arene C-H Bond Metalation, J. Am. Chem. Soc. 136, 6326-6332 (2014).

*以上信息由高級(jí)會(huì)員個(gè)人更新和維護(hù)。